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Lesson 3 of 11Matter, Chemical Trends & Bonding
Unit 1 · Lesson 3 of 11

Organization of the Periodic Table

How the periodic table is arranged into periods, groups, and families — and why that arrangement isn't arbitrary.

5 min read11 practice questionsAsk AI about this →

Key things to remember

  1. 1Period number = number of electron shells in use.
  2. 2Group number (main groups) = number of valence electrons (subtract 10 for groups 13–18).
  3. 3Metals lose electrons to form positive ions (cations); nonmetals gain electrons to form negative ions (anions).
  4. 4Metalloids sit along the staircase line and have intermediate, semiconductor-like properties.
  5. 5Elements in the same family share similar chemical properties because they share the same valence electron count.

The periodic table isn't just a list of elements — its layout encodes real chemistry. Elements are arranged in order of increasing atomic number, but the table wraps into rows and columns specifically so that elements with similar properties line up in the same column. That's the entire point of the design. When Dmitri Mendeleev built the first successful table in 1869, he trusted that pattern so much that he left gaps for elements nobody had found yet and predicted their properties. His "eka-silicon", predicted to sit below silicon with an atomic mass near 72 and a high melting point, was discovered in 1886 as germanium, with almost exactly the properties he forecast. The modern periodic law says that when elements are arranged by atomic number, their properties repeat in a regular (periodic) way — and the rest of this lesson explains why they repeat.

Periodic Table of the Elements1H2He3Li4Be5B6C7N8O9F10Ne11Na12Mg13Al14Si15P16S17Cl18Ar19K20Ca21Sc22Ti23V24Cr25Mn26Fe27Co28Ni29Cu30Zn31Ga32Ge33As34Se35Br36Kr37Rb38Sr39Y40Zr41Nb42Mo43Tc44Ru45Rh46Pd47Ag48Cd49In50Sn51Sb52Te53I54Xe55Cs56Ba57La72Hf73Ta74W75Re76Os77Ir78Pt79Au80Hg81Tl82Pb83Bi84Po85At86Rn87Fr88Ra89Ac104Rf105Db106Sg107Bh108Hs109Mt110Ds111Rg112Cn113Nh114Fl115Mc116Lv117Ts118Og58Ce59Pr60Nd61Pm62Sm63Eu64Gd65Tb66Dy67Ho68Er69Tm70Yb71Lu90Th91Pa92U93Np94Pu95Am96Cm97Bk98Cf99Es100Fm101Md102No103LrLanthanidesActinidesAlkali metalAlkaline earth metalTransition metalLanthanideActinidePost-transition metalMetalloidNonmetalHalogenNoble gas
Fig 1Periods (rows), groups (columns), and the metal / metalloid / nonmetal regions of the periodic table.

Periods (rows)

A period is a horizontal row. The period number tells you how many electron shells (energy levels) an atom of that element uses. Elements in Period 3 (Na through Ar) all have electrons occupying shells 1, 2, and 3. Moving left to right across a period, protons and electrons are added one at a time to the same outer shell. That also explains the lengths of the first rows. Period 1 has only two elements (H and He) because shell 1 holds just 2 electrons. Periods 2 and 3 each have eight elements because their outer shells fill with 8. When a shell is full, the next element has to start a new shell — and a new row — which is why every period begins with a very reactive metal holding a single valence electron and ends with an unreactive noble gas.

Groups (columns) and families

A group (or family) is a vertical column. Elements in the same group have the same number of valence (outer-shell) electrons, which is why they show similar chemical behaviour — valence electrons are what control bonding. For main-group elements, the group number (1, 2, 13–18) tells you the number of valence electrons directly (for groups 13–18, subtract 10).

FamilyGroup #Valence e⁻Key trait
Alkali metals11Extremely reactive, soft metals; never found free in nature
Alkaline earth metals22Reactive metals, less so than Group 1
Transition metals3–12variesForm multiple ion charges, often coloured compounds
Halogens177Very reactive nonmetals; form salts with metals
Noble gases188 (2 for He)Full outer shell; essentially unreactive

You can watch the family resemblance in the lab. Every alkali metal reacts with water to make hydrogen gas and a metal hydroxide, and the reaction gets more violent down the group: lithium fizzes steadily, sodium melts into a ball and skates across the surface, and potassium bursts into a lilac flame. The halogens all exist as diatomic molecules (, , , ), and their state changes smoothly down the group — fluorine and chlorine are gases, bromine is a red-brown liquid and iodine is a grey-black solid at room temperature. The noble gases are so unreactive that they are used where nothing must react: argon fills incandescent bulbs and shields welds, and helium lifts balloons safely.

GroupValence e⁻Easiest changeTypical ionExample
11Lose 11+Na⁺
22Lose 22+Mg²⁺
133Lose 33+Al³⁺
155Gain 33−N³⁻
166Gain 22−O²⁻
177Gain 11−Cl⁻
188NoneNo ionAr
Atoms lose or gain the fewest electrons needed to reach a full outer shell like the nearest noble gas.

Metals, nonmetals, and metalloids

  • Metals (left/centre of the table): shiny, malleable, ductile, good conductors, tend to lose electrons and form cations.
  • Nonmetals (upper right): dull, brittle if solid, poor conductors, tend to gain electrons and form anions.
  • Metalloids (along the staircase line, e.g. B, Si, Ge, As, Sb, Te): properties in between; several are semiconductors used in electronics.
Tip
Hydrogen sits above Group 1 but is not an alkali metal — it's a nonmetal. It's placed there only because it has 1 valence electron, matching the group's electron count.
AMetals
  • About four out of every five elements
  • All solids at SATP except mercury (a liquid)
  • Loosely held valence electrons move freely, so they conduct heat and electricity
  • Atoms slide past each other, so they bend (malleable) and draw into wires (ductile)
  • Lose electrons to form positive ions
BNonmetals
  • Only about 17 elements: hydrogen plus the upper right, including the noble gases
  • Eleven are gases at SATP, bromine is a liquid, the rest are solids
  • Valence electrons are held tightly, so they are insulators
  • Solid nonmetals such as sulfur shatter when struck (brittle)
  • Gain electrons to form negative ions, or share electrons with other nonmetals

Reading the table like a chemist

  1. Find the element's period: that is how many electron shells it uses.
  2. Find its group: for main-group elements, that gives the valence electrons (groups 1–2 directly; groups 13–18 subtract 10).
  3. Combine the two to write the electron arrangement: fill the inner shells completely, then put the valence electrons in the last shell.
  4. Check its region: left of the staircase means metal (forms a cation), right means nonmetal (forms an anion), on the line means metalloid.
  5. Predict its ion from the fewest electrons it must lose or gain to match the nearest noble gas.

Worked examples

Reveal one step at a time and try to beat it to the next line.

Example 1
Without looking it up, state the period and group of phosphorus (P, ), and its number of valence electrons.
Example 2
Classify sodium, silicon, and sulfur as metal, metalloid, or nonmetal, and justify each.
Example 3
Element X is in Period 3 and Group 2. Identify X, write its electron arrangement, predict the ion it forms, and predict two of its properties.

Where marks get lost

  • Assuming hydrogen is an alkali metal because it's drawn above Group 1 — it's a nonmetal.
  • Using the group number directly as the valence electron count for groups 13–18 without subtracting 10.
  • Thinking transition metals (groups 3–12) follow the simple group-number-equals-valence-electrons rule — they don't; their bonding behaviour is more complex and covered separately.
  • Confusing period (row, shells) with group (column, valence electrons) — they describe different things.
  • Assuming all metalloids behave identically — their properties vary and are genuinely intermediate, not a fixed single behaviour.

Flashcards 10

Period
Group / family
Valence electrons
Alkali metals
+ 6 more

Practice

1
What does the period number of an element directly indicate?
2
How many valence electrons does an atom in Group 16 have?
3
Name the family found in Group 18 of the periodic table.
4
Which of these is a metalloid?
5
Order these elements by increasing period number (fewest electron shells first).
  1. 1Magnesium (Mg)
  2. 2Cesium (Cs)
  3. 3Potassium (K)
  4. 4Lithium (Li)
6
Match each family name to its group number.
Alkali metals
Alkaline earth metals
Halogens
Noble gases
7
Why does hydrogen sit above Group 1 even though it is not a metal?
8
How many electron shells are occupied in a bromine atom (Br, Period 4, Group 17)?
9
Which ion is aluminum (Group 13) most likely to form?
10
Name the element in Period 3, Group 17.
11
Mendeleev left a gap below silicon and predicted an element with properties like silicon's. Why was he confident the gap belonged there?

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