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Lesson 2 of 8The Nature of Matter
Unit 3 · Lesson 2 of 8

Physical and Chemical Properties and Changes

How to describe a substance by its physical and chemical properties, how to calculate density, how to tell a physical change from a chemical change using five clues, and how to read the hazard symbols on household products.

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Key things to remember

  1. 1A physical property can be observed without making a new substance; a chemical property describes how a substance reacts to form new substances.
  2. 2Density: , usually in g/cm³ or g/mL (1 mL = 1 cm³).
  3. 3Water has a density of about 1.00 g/mL: less dense objects float, denser objects sink.
  4. 4A physical change keeps the same substance; a chemical change makes a new substance.
  5. 5Five clues of a chemical change: new colour, gas formed, precipitate, heat or light, new odour. They are clues, not proof.
  6. 6On Canadian household products, an octagon frame means the contents are dangerous and a triangle frame means the container is dangerous.

Why does a log float but a nail sink? Why does a cut apple turn brown, while melted chocolate can harden back into a bar? Chemists answer questions like these by looking at properties, the characteristics that describe a substance, and changes, what happens when a substance is heated, mixed or left out in the air. Knowing the properties of a substance tells you how to use it safely: which metal makes a good pot, which cleaner should never be mixed with another, and why oil from a spill spreads across the top of the ocean.

A physical property is a characteristic you can observe or measure without turning the substance into something new. Some are qualitative (described in words, such as colour or texture) and some are quantitative (measured with a number and unit, such as melting point or density).

Physical propertyMeaningExample
StateSolid, liquid or gas at room temperatureMercury is a metal, yet it is a liquid at room temperature
Colour and lustreLustre is how shiny a surface isCopper is reddish-brown and lustrous; sulfur is dull yellow
Melting and boiling pointTemperatures at which a solid melts or a liquid boilsWater melts at 0 °C and boils at 100 °C
HardnessHow easily a substance is scratchedDiamond scratches glass; talc can be scratched by a fingernail
MalleabilityCan be hammered or rolled into thin sheetsAluminium foil
DuctilityCan be pulled into a wireCopper wiring in a house
ConductivityLets heat or electric current pass throughMetal pots conduct heat; plastic handles do not
SolubilityHow much dissolves in a liquid such as waterSugar is very soluble in water; sand is not
ViscosityHow thick a liquid is, or how slowly it poursHoney is more viscous than water
DensityMass in a given volumeLead (11.3 g/cm³) is much denser than wood (about 0.5 g/cm³)
Common physical properties. Each can be observed without making a new substance.

Density

Density is how much mass is packed into a given volume. A brick and a block of foam can be the same size, but the brick is much heavier because its particles are heavier and packed more tightly. To find density, divide the mass by the volume. Mass is usually in grams (g), and volume in cubic centimetres (cm³) for solids or millilitres (mL) for liquids. One millilitre equals one cubic centimetre, so g/mL and g/cm³ mean the same thing.

Density equals mass divided by volume. Rearrange it to find mass or volume.

Pure water has a density of about 1.00 g/mL. An object that is less dense than water floats, and one that is denser sinks. Each pure substance has its own density, so density can help identify an unknown material: aluminium is 2.70 g/cm³, iron is 7.87 g/cm³, copper is 8.96 g/cm³ and gold is 19.3 g/cm³. To find the volume of an irregular object such as a rock, use water displacement: read the water level in a graduated cylinder, gently drop the object in, and read the new level. The rise in water level is the object's volume.

Chemical properties and changes

A chemical property describes how a substance reacts to form new substances. You can only observe it by trying the reaction. Examples are combustibility (whether it burns), how it reacts with oxygen (iron rusts, gold does not), how it reacts with acids or water, and whether it breaks down when heated. A physical change changes the form or state of a substance but not what it is made of: melting, freezing, boiling, dissolving, cutting and bending. A chemical change (a chemical reaction) produces one or more new substances with new properties: burning, rusting, cooking an egg, and baking soda fizzing in vinegar.

Physical changesame substance, new form or sizeMelting icesolid water → liquid waterDissolving sugarsugar spreads out in waterCutting papersmaller pieces, still paperChemical changea new substance formsBurning woodmakes ash and new gasesRusting ironiron + oxygen → iron oxideBaking soda + vinegarmakes carbon dioxide gasFive clues that a chemical change may have happenedColour changeGas bubblesPrecipitatea solid forms in a liquidHeat or lightgiven offChange in odourClues, not proof: a physical change can show some too (boiling water makes bubbles).
Fig 1Physical changes (melting ice, dissolving sugar, cutting paper) keep the same substance, while chemical changes (burning, rusting, baking soda and vinegar) make a new one. The five clues of a chemical change are a colour change, gas bubbles, a precipitate, heat or light, and a change in odour; they are clues, not proof.
  1. A new colour appears, such as a cut apple turning brown.
  2. A gas forms (bubbles or fizzing) when you did not boil the liquid, such as baking soda in vinegar.
  3. A precipitate forms: a solid appears when two liquids are mixed.
  4. Heat or light is given off or taken in, such as a burning candle, or baking soda and vinegar turning slightly colder as they fizz.
  5. A new odour appears, such as the smell of rotting food or burnt toast.
Clues, not proof
Each clue can also show up in a physical change. Boiling water makes bubbles, and a light bulb gives off light, but no new substance forms. The strongest evidence of a chemical change is a new substance with different properties, and chemical changes are often hard to reverse. When you see two or more clues together, a chemical change is very likely.
Properties that matter for ecosystems
Crude oil is less dense than water and does not dissolve in it, so an oil spill spreads across the water surface and coats birds and shorelines. Ice is less dense than liquid water, so lakes freeze from the top down and fish survive the winter in the liquid water below. Road salt dissolves in meltwater (a physical change) and washes into streams, where it can harm freshwater life. Acid rain reacts with limestone and marble (a chemical change), slowly dissolving statues and changing the chemistry of lakes.

Household products. Many cleaners, paints and fuels at home have chemical properties that make them dangerous if they are misused. In Canada, consumer chemical products carry hazard symbols. The picture inside the frame tells you the type of hazard, and the shape of the frame tells you whether the danger is the contents or the container. A signal word, CAUTION, DANGER or EXTREME DANGER, tells you how serious the hazard is.

SymbolHazardHousehold example
Skull and crossbonesPoisonous: harmful if swallowed, breathed in or absorbedWindshield washer fluid, some pesticides
FlameFlammable: catches fire easilyGasoline, lighter fluid, some aerosol sprays
Hand and object being eaten away by liquidCorrosive: burns skin and eyes and damages materialsOven cleaner, drain cleaner
Bursting containerExplosive container: may burst if heated or puncturedAerosol cans, propane cylinders
Octagon frame (stop sign shape)The contents are dangerousUsed with the poison, flame and corrosive symbols
Triangle frame (point down)The container is dangerousUsed with the explosive container symbol
Hazard symbols on Canadian consumer chemical products. Workplace and lab chemicals use the WHMIS pictograms instead.
Never mix cleaners
Bleach mixed with ammonia-based glass cleaner, or with acidic toilet bowl cleaners, reacts to release toxic gases. That is a dangerous chemical property. Use one product at a time, keep products in their original labelled containers, and store them out of reach of children.

Worked examples

Reveal one step at a time and try to beat it to the next line.

Example 1
A small metal block has a mass of 54.0 g and a volume of 20.0 cm³. Find its density and use it to identify the metal (aluminium 2.70, iron 7.87, copper 8.96 g/cm³).
Example 2
A rock has a mass of 66.0 g. When it is lowered into a graduated cylinder, the water level rises from 50.0 mL to 72.0 mL. Find the rock's density. Will it float in water?
Example 3
Olive oil has a density of 0.92 g/mL. What is the mass of 250 mL of olive oil?
Example 4
Classify each as a physical or chemical change: (a) a puddle drying up, (b) a silver spoon turning black, (c) toast burning.

Where marks get lost

  • Calling dissolving a chemical change. When sugar dissolves, it is still sugar; evaporating the water gets it back. Dissolving is a physical change.
  • Treating any bubbles as proof of a chemical change. Boiling water bubbles because liquid water turns into water vapour, which is a physical change.
  • Dividing the wrong way in density. It is mass divided by volume, not volume divided by mass: 54 g in 20 cm³ is 2.7 g/cm³, not 0.37 g/cm³.
  • Using the final water level as the volume in water displacement. The object's volume is the change: final level minus starting level.
  • Thinking heavier objects always sink. A huge log floats and a tiny pebble sinks; what matters is density, not mass.

Flashcards 8

Physical property
Chemical property
Density formula
Malleable
+ 4 more

Practice

1
A piece of metal has a mass of 39.5 g and a volume of 5.00 cm³. What is its density in g/cm³? Give your answer to two decimal places.
g/cm³
2
Water rises from 30.0 mL to 45.0 mL when a 40.5 g stone is dropped in. What is the stone's density in g/mL? Give your answer to one decimal place.
g/mL
3
Gasoline has a density of about 0.75 g/mL. What is the mass of 40 mL of gasoline, in grams?
g
4
Which is a chemical property of iron?
5
Which observation is the strongest evidence that a chemical change has happened?
6
Match each change to the best description.
Chocolate melting in your hand
Wood burning in a campfire
Cutting paper into strips
Milk going sour
7
A can of spray paint shows a bursting-container symbol inside a triangle. What does the triangle frame mean?
8
Name the physical property that describes a metal being hammered into thin sheets.
9
Why do lakes freeze from the top down, which lets fish survive the winter?

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