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Lesson 5 of 8The Nature of Matter
Unit 3 · Lesson 5 of 8

The Periodic Table

How the periodic table is organized into periods and groups, how to read an element box, how metals, non-metals and metalloids differ, and the four main chemical families: alkali metals, alkaline earth metals, halogens and noble gases.

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Key things to remember

  1. 1The modern periodic table is arranged in order of increasing atomic number.
  2. 2A period is a horizontal row (7 periods); a group or family is a vertical column (18 groups).
  3. 3Metals are left of the staircase line, non-metals to the right, and metalloids along it.
  4. 4Metals are usually shiny, malleable, ductile and good conductors; non-metals are usually dull, brittle and poor conductors.
  5. 5Group 1: alkali metals; group 2: alkaline earth metals; group 17: halogens; group 18: noble gases.
  6. 6Elements in the same group have similar chemical properties.

There are 118 known elements, from the hydrogen in water to the gold in a medal. Learning each one separately would be overwhelming. Instead, chemists use the periodic table, a chart that arranges the elements so that ones with similar properties line up together. It works a bit like a grocery store: if you know where the cereal aisle is, you know where to find every cereal. If you know where an element sits on the table, you can predict a lot about how it behaves.

In 1869 the Russian chemist Dmitri Mendeleev wrote the properties of the roughly 63 elements known at the time on cards and arranged them in order of atomic mass. He noticed that similar properties repeated at regular intervals, so he placed similar elements in the same column. Boldly, he left gaps where no known element fit and predicted the properties of the missing elements. When germanium was discovered in 1886, its properties matched his predictions closely, which convinced other scientists his table was right. Today the table is arranged in order of atomic number (number of protons), an improvement made by Henry Moseley in 1913.

Periodic Table of the Elements1H2He3Li4Be5B6C7N8O9F10Ne11Na12Mg13Al14Si15P16S17Cl18Ar19K20Ca21Sc22Ti23V24Cr25Mn26Fe27Co28Ni29Cu30Zn31Ga32Ge33As34Se35Br36Kr37Rb38Sr39Y40Zr41Nb42Mo43Tc44Ru45Rh46Pd47Ag48Cd49In50Sn51Sb52Te53I54Xe55Cs56Ba57La72Hf73Ta74W75Re76Os77Ir78Pt79Au80Hg81Tl82Pb83Bi84Po85At86Rn87Fr88Ra89Ac104Rf105Db106Sg107Bh108Hs109Mt110Ds111Rg112Cn113Nh114Fl115Mc116Lv117Ts118Og58Ce59Pr60Nd61Pm62Sm63Eu64Gd65Tb66Dy67Ho68Er69Tm70Yb71Lu90Th91Pa92U93Np94Pu95Am96Cm97Bk98Cf99Es100Fm101Md102No103LrLanthanidesActinidesAlkali metalAlkaline earth metalTransition metalLanthanideActinidePost-transition metalMetalloidNonmetalHalogenNoble gas
Fig 1The full periodic table of 118 elements. Each box shows the atomic number and symbol, and the colours sort the elements into alkali metals, alkaline earth metals, transition metals, lanthanides, actinides, post-transition metals, metalloids, non-metals, halogens and noble gases.

Each box on a full periodic table usually gives the atomic number, the symbol (one or two letters, the first always a capital, such as C for carbon or Na for sodium, from its Latin name natrium), the name and the atomic mass. A horizontal row is called a period; there are 7 periods. A vertical column is called a group or family; there are 18 groups, numbered 1 to 18 from left to right. Elements in the same group have similar chemical properties.

Group numberPeriod1234567891011121314151617181234HHeLiBeBCNOFNeNaMgAlSiPSClArKCaScTiVCrMnFeCoNiCuZnGaGeAsSeBrKr← Hydrogen: placed in group 1, but it is a non-metalMetalsNon-metalsMetalloidsstaircase line: metals are to its leftTransition metalsgroups 3 to 12Alkali metalsgroup 1Alkaline earthmetals, group 2Halogensgroup 17Noble gasesgroup 18Periods 5 to 7 are not shown. Further down, antimony (Sb) and tellurium (Te) are alsometalloids, and polonium (Po) and astatine (At) are sometimes counted as metalloids.
Fig 2An outline of the first four periods with group numbers across the top and period numbers down the side. Metals, non-metals and metalloids are shaded differently, with the metalloids along the staircase line, and the alkali metals (group 1), alkaline earth metals (group 2), halogens (group 17) and noble gases (group 18) are labelled. Hydrogen is marked as a special case.

Metals, non-metals and metalloids

PropertyMetalsNon-metalsMetalloids
Where on the tableLeft of the staircase line (most elements)Right of the staircase line, plus hydrogenAlong the staircase line: boron, silicon, germanium, arsenic, antimony, tellurium
State at room temperatureSolid, except mercury (liquid)Many are gases; some solids; bromine is a liquidSolid
AppearanceShiny (lustrous)Usually dullCan be shiny or dull
When hammeredMalleable (flattens) and ductile (can be drawn into wire)Solids are brittle (shatter)Brittle
ConductivityGood conductors of heat and electricityUsually poor conductors (insulators)Semiconductors: conduct a little, and the amount can be controlled
ExamplesIron, copper, aluminium, gold, sodiumOxygen, nitrogen, carbon, sulfur, chlorineSilicon (computer chips), boron
Comparing metals, non-metals and metalloids. About three quarters of the elements are metals.
Watch for exceptions
These are general patterns, not iron rules. Mercury is a metal but is liquid at room temperature. Graphite, a form of the non-metal carbon, conducts electricity well, which is why it is used in battery electrodes. Diamond, another form of carbon, is a non-metal yet the hardest natural substance.

Chemical families

FamilyGroupMembersPropertiesUses
Alkali metals1Lithium, sodium, potassium, rubidium, cesium, franciumSoft enough to cut with a knife; react with water, more and more violently going down the group, giving off hydrogen gas; stored under oilLithium in rechargeable batteries; sodium compounds in table salt
Alkaline earth metals2Beryllium, magnesium, calcium, strontium, barium, radiumReactive, but less than the alkali metals; harderMagnesium in fireworks and light alloys; calcium compounds in bones, chalk and cement
Halogens17Fluorine, chlorine, bromine, iodine, astatineVery reactive non-metals; form salts with metals; at room temperature fluorine and chlorine are gases, bromine is a liquid and iodine is a solidChlorine to disinfect drinking water and pools; fluoride in toothpaste; iodine as an antiseptic
Noble gases18Helium, neon, argon, krypton, xenon, radonColourless gases; very unreactive (only a few compounds of the heavier ones, such as xenon, are known)Helium in balloons; neon in signs; argon in light bulbs and as a shielding gas in welding
The four main chemical families. The transition metals in groups 3 to 12, such as iron, copper, silver and gold, are another large group of useful metals.
Hydrogen is a special case
Hydrogen sits at the top of group 1 because it has 1 electron, like the alkali metals. But it is a colourless, non-metal gas and does not behave like an alkali metal, so it is not part of that family.
Careers with the periodic table
Welders choose filler metals to match the metals they join and use argon, a noble gas, to shield hot metal from oxygen in the air so the weld does not weaken. Materials engineers combine elements into alloys such as stainless steel (iron with chromium, and often nickel) to make products stronger, lighter or rust-resistant.

Worked examples

Reveal one step at a time and try to beat it to the next line.

Example 1
An element box shows 12, Mg, magnesium, 24.31. Where is magnesium on the table, and what kind of element is it?
Example 2
A grey, shiny solid shatters when hit with a hammer and conducts a small amount of electricity. Is it a metal, a non-metal or a metalloid?
Example 3
Mendeleev predicted an element he called eka-silicon, with atomic mass about 72 and density about 5.5 g/cm³. Germanium, found in 1886, has atomic mass 72.6 and density 5.3 g/cm³. Why was this match important?

Where marks get lost

  • Mixing up periods and groups. Periods are rows (think of a sentence ending in a period, read across); groups are columns.
  • Calling hydrogen an alkali metal because it is in group 1. Hydrogen is a non-metal gas.
  • Saying all metals are solid or all non-metals are poor conductors. Mercury is a liquid metal, and graphite (carbon) conducts electricity.
  • Thinking the table is ordered by atomic mass. Mendeleev used atomic mass, but the modern table uses atomic number.
  • Confusing the symbol with the first letter of the name. Some symbols come from Latin names: Na (sodium), K (potassium), Fe (iron), Cu (copper), Ag (silver), Au (gold), Pb (lead).

Flashcards 9

Period
Group (family)
Alkali metals
Alkaline earth metals
+ 5 more

Practice

1
An element is shiny, can be hammered into a sheet and conducts electricity well. It is most likely a
2
In which period and group is chlorine (atomic number 17)?
3
Match each element to its chemical family.
Potassium
Calcium
Iodine
Neon
4
Which element is a metalloid used in computer chips?
5
What is the family name of group 18, the very unreactive gases?
6
How is the modern periodic table ordered?
7
Which of these is an exception to the usual properties of its type of element (metal or non-metal)?
8
How many groups (columns) does the modern periodic table have?
9
Why are alkali metals stored under oil?

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